A thermodynamic model of non-ionic surfactants' micellization in the presence of polyoxometalates
نویسندگان
چکیده
منابع مشابه
A Computer Simulation and Molecular-Thermodynamic Framework to Model the Micellization of Ionic Branched Surfactants in Aqueous Solution
Surfactants, or surface active agents, are chemicals exhibiting amphiphilic behavior toward a solvent. This amphiphilic character leads to increased activity at interfaces and to self-assembly into micellar aggregates beyond a threshold surfactant concentration, referred to as the critical micelle concentration (CMC), in bulk solutions. As a result of these unique attributes, surfactants are us...
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Specific ion effects on the self-assembly of ionic surfactants: a molecular thermodynamic theory of micellization with dispersion forces.
The self-assembly of amphiphilic molecules is a key process in numerous biological and chemical systems. When salts are present, the formation and properties of molecular aggregates can be altered dramatically by the specific types of ions in the electrolyte solution. We present a molecular thermodynamic model for the micellization of ionic surfactants that incorporates quantum dispersion force...
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ژورنال
عنوان ژورنال: Journal of Molecular Liquids
سال: 2019
ISSN: 0167-7322
DOI: 10.1016/j.molliq.2019.111280